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Could ‘dirty’ Ammonia be the clean fuel of the future?

image credit: Photo courtesy of Unsplash

 

The ammonia market is worth about 33 billion dollars accounting for a staggering 1.8% of global carbon emissions. Produced under super high pressures from Hydrogen and Nitrogen; Ammonia production is energy intensive and more than a little bit ‘dirty’ when it comes to carbon emissions.

Ammonia in liquid form provides a tantalizing potential for a green fuel; even if it does have a few challenges!

Could ammonia really be the fuel of the future? I’ve recently been looking at Hydrogen and it’s clear that one of the biggest challenges of Hydrogen as a fuel is it’s density in gaseous form along with high costs storing and transporting it.... Ammonia in liquid form provides a tantalizing potential solution even if it does have a few challenges (Ammonia is explosive, toxic and very smelly!). Potential early applications for ammonia as a fuel include shipping and maybe even aviation!

When I discussed my predictions for the next 10 years of energy I didn't cover Ammonia - after much discussion and some further research I'm starting to think that maybe Ammonia has the potential to be a 'black swan' technology in some specific sectors.

How is Ammonia made?

The feed stock for Ammonia (NH3) is simply Nitrogen and Hydrogen. Nitrogen can be relatively efficiently extracted from the air through cryogenic (cooling the air so Nitrogen drops out) processes, whereas Hydrogen is a bit trickier. Typically, steam is used at very high temperatures to strip Hydrogen away from the Hydrocarbon atoms in Methane or Coal. This produces a lot of carbon dioxide!

Next the two gases are fed into a reactor and pressurised to about 250 bar in a process which has changed little in 100 years called the Haber-Bosch process. In this process the Hydrogen atoms from then feed-stock are combined with Nitrogen from the air. All of which is quite energy intensive as energy is needed to extract Nitrogen as well as pump up the two gasses to such high pressures.

What about Safety and the local environment?

Ammonia does come with its challenges! A quick google on risks of ammonia comes up with this:

‘Exposure to high concentrations of ammonia in air causes immediate burning of the eyes, nose, throat and respiratory tract and can result in blindness, lung damage or death. Inhalation of lower concentrations can cause coughing, and nose and throat irritation’

So not the nicest chemical to get exposed to! On top of the potential health impacts its also corrosive and explosive so presents some interesting challenges to engineers…

However, engineers are well used to handling challenging chemicals and ammonia, in fact in the United Stated there are already 2000 miles of ammonia pipelines along with a substantial infrastructure for ammonia manufacture and distribution. So its certainly not impossible that ammonia might be the right 'green' fuel for some applications.

pink pipe

In fact, existing hydrocarbons are distributed vie pipelines, trucks, petrol stations etc. Petrol and Diesel come with their own challenges in terms of environmental and explosion hazards.

Finally, Ammonia is regularly used in refrigeration and heat pumps so its highly likely you are passing near safely stored ammonia regularly in our everyday lives at sites such as hospitals, supermarkets among many others!

Would Ammonia be more expensive than Hydrogen?

A study by the Royal Society highlight substantial savings using Ammonia in Rail, Shipping and Heavy Road Transport... in fact nearly 80% reduction to that of Hydrogen gas and a third of the costs of liquefied Hydrogen.

Rail, Heavy Road and Shipping are the three sectors with real potential for utilising Ammonia as a green fuel.

These highlights Ammonia's real potential in transport. It is perhaps these three areas where Ammonia has some really interesting potential as a fuel for the future.

How Green could Ammonia be?

Ammonia could absolutely be zero carbon. If you can make green Hydrogen (either with green electricity or carbon capture & storage) and green electricity you can make green ammonia. You just need a lot of green energy! I do think the focus now could should be on de-carbonising the world’s existing ammonia demand… this would then provide a sound footing for Ammonia to potentially be used as a green fuel!

Planet Earth First

 

 

 

 

John Armstrong's picture

Thank John for the Post!

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Discussions

Charley Rattan's picture
Charley Rattan on Mar 25, 2020 5:38 pm GMT

Interesting post.  A number of early adopters are indeedmoving into the Ammonia market and are currently greening its production. 

John Armstrong's picture
John Armstrong on Mar 26, 2020 2:24 pm GMT

It still feels quite early doesn't it? But for shipping I think it definately has potential.

Charley Rattan's picture
Charley Rattan on Mar 27, 2020 7:13 am GMT

The martitime sector is of great interest

Gary Hilberg's picture
Gary Hilberg on Mar 27, 2020 2:27 pm GMT

John - certainly research has to be done to make any new technology viable.  My concern is that all of these "green" alternatives have this very simple assumption - 100% renewable power to produce them.  Similar to ethanol as fuel replacement, ignore the environmental impact of land, diesel, fertilizer (ammonia), processing and we have a green fuel.  The US is still less than 40% non-carbon electricity - so we have to buildout 60% more energy generation AND then produce adequate green electricity for energy cycles that have less than a 50% round trip efficiency.  We also have to consider the use of fossil fuels for heating and the massive summer storage and winter usage of that energy.   Research and discussion needs to happen but in context of where the energy transition is at this time.  I agree finding a green alternative to the massive current demand for Ammonia mainly for fertilizer is a better focus, the first step is stop using coal to produce Ammonia!

John Armstrong's picture
John Armstrong on May 1, 2020 8:50 am GMT

I agree Gary...I think these solutions are sold as 'green' when in reality they are just transport vectors.... Hydrogen, Ammonia, Electricty are not green in themselves they are just a way to move energy around.

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